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Title: Robust, ultrasmall organosilica nanoparticles without silica shells
Authors: Murray, EoinBorn, PhilipWeber, AnikaKraus, Tobias
Publishers Version: https://doi.org/10.1007/s11051-014-2462-7
Issue Date: 2014
Published in: Journal of Nanoparticle Research, Volume 16, Issue 7, Page 1-8
Publisher: Heidelberg : Springer
Abstract: Traditionally, organosilica nanoparticles have been prepared inside micelles with an external silica shell for mechanical support. Here, we compare these hybrid core–shell particles with organosilica particles that are robust enough to be produced both inside micelles and alone in a sol–gel process. These particles form from octadecyltrimethoxy silane as silica source either in microemulsions, resulting in water-dispersible particles with a hydrophobic core, or precipitate from an aqueous mixture to form particles with both hydrophobic core and surface. We examine size and morphology of the particles by dynamic light scattering and transmission electron microscopy and show that the particles consist of Si–O–Si networks pervaded by alkyl chains using nuclear magnetic resonance, infrared spectroscopy, and thermogravimetric analysis.
Keywords: Nanoparticle synthesis; Stöber process; organosilica; micelles
DDC: 540
License: This document may be downloaded, read, stored and printed for your own use within the limits of § 53 UrhG but it may not be distributed via the internet or passed on to external parties.
Dieses Dokument darf im Rahmen von § 53 UrhG zum eigenen Gebrauch kostenfrei heruntergeladen, gelesen, gespeichert und ausgedruckt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden.
Appears in Collections:Chemie



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