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| File | Description | Size | Format | |
|---|---|---|---|---|
| Joksch et al 2019, Intermolecular hydrogen bonding in isostructural.pdf | 569,89 kB | Adobe PDF | View/Open |
| Title: | Intermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt) |
| Authors: | Joksch, M.; Spannenberg, A.; Beweries, T. |
| Publishers Version: | https://doi.org/10.1107/S2056989019008491 |
| Issue Date: | 2019 |
| Published in: | Acta Crystallographica Section E: Crystallographic Communications Vol. 75 (2019) |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | In the crystal structure of the isostructural title compounds, namely {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridopalladium(II), [Pd(C22H39O3P2)Cl], 1, and {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridoplatinum(II), [Pt(C22H39O3P2)Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an interaction of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand. |
| Keywords: | Crystal structure; Hydrogen bonding; Palladium; pincer complexes; Platinum |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to License: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License
