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Title: Intermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt)
Authors: Joksch, M.Spannenberg, A.Beweries, T.
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Issue Date: 2019
Published in: Acta Crystallographica Section E: Crystallographic Communications Vol. 75 (2019)
Publisher: Chester : International Union of Crystallography
Abstract: In the crystal structure of the isostructural title compounds, namely {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridopalladium(II), [Pd(C22H39O3P2)Cl], 1, and {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridoplatinum(II), [Pt(C22H39O3P2)Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an interaction of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.
Keywords: Crystal structure; Hydrogen bonding; Palladium; pincer complexes; Platinum
DDC: 540
License: CC BY 4.0 Unported
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