Please use this identifier to cite or link to this item: https://oar.tib.eu/jspui/handle/123456789/4944
Title: Effects of Promoter on Structural and Surface Properties of Zirconium Oxide-Based Catalyst Materials
Authors: Borovinskaya, E.S.Oswald, S.Reschetilowski, W.
Publishers Version: https://doi.org/10.3390/molecules25112619
Issue Date: 2020
Published in: Molecules Vol. 25 (2020), No. 11
Publisher: Basel : MDPI AG
Abstract: Ternary mixed oxide systems CuO/ZnO/ZrO2 and CuO/NiO/ZrO2 were synthesized by one-pot synthesis for a better understanding of the synthesis-property relationships of zirconium oxide-based catalyst materials. The prepared mixed oxide samples were analysed by a broad range of characterisation methods (XRD, N2-physisorption, Temperature-Programmed Ammonia Desorption (TPAD), and XPS) to examine the structural and surface properties, as well as to identify the location of the potential catalytically active sites. By XPS analysis, it could be shown that a progressive enrichment of the surface composition with copper takes place by changing from ZnO to NiO as a promoter. Thus, by addition of the second component, not only electronic but also the geometric properties of active sites, i.e., copper species distribution within the catalyst surface, can be affected in a desired way.
Keywords: catalyst surface; copper species; NiO promoter; one-pot synthesis; zirconium oxide; ZnO promoter
DDC: 540
License: CC BY 4.0 Unported
Link to License: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie



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