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Lau et al 1999, Molecular Dynamics Investigated by.pdf411,62 kBAdobe PDFView/Open
Title: Molecular dynamics investigated by temporally two-dimensional coherent Raman spectroscopy
Authors: Lau, A.Pfeiffer, M.Kozich, V.Kummrow, A.
Publishers Version: https://doi.org/10.1155/1999/41281
Issue Date: 1999
Published in: Laser Chemistry Vol. 19 (1999), No. 1-4
Publisher: Routledge : Taylor and Francis Inc.
Abstract: A six-wave set-up is described to determine molecular dynamics in the condensed phase. Applying two independent time delays between excitation and probe pulses additional information on the dynamics should be obtainable. We show experimentally that such investigations can be carried out with noisy light having intensity fluctuations in the femtosecond region. As first result we found a fast relaxation time in neat nitrobenzene of 100 fs, becoming even faster in mixtures with low viscosity liquids. Switching on a Raman resonance yields a longer relaxation time, which could be explained by an additional contribution by that vibration.
Keywords: Fifth order nonlinearity; Kerr effect; Nonlinear spectroscopy; Raman
DDC: 530
License: CC BY 3.0 Unported
Link to License: https://creativecommons.org/licenses/by/3.0/
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