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Schulz et al 2010, +-1,2-Bis2R,5R-2,5-di­ethyl­phospho­lan-1-yl.pdf317.42 kBAdobe PDFView/Open
Title: (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate
Authors: Schulz, S.Fischer, C.Drexler, H.-J.Heller, D.
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Issue Date: 2010
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 66 (2010), No. 11
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [Rh(C8H12)(C18H 36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate 2, 2-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) is 14.0 (1)°. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio.
Keywords: Crystal structure; Chemistry; Crystallography
DDC: 540
License: CC BY 4.0 Unported
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Appears in Collections:Chemie

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