Please use this identifier to cite or link to this item:
https://oar.tib.eu/jspui/handle/123456789/5415
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Schulz et al 2010, +-1,2-Bis2R,5R-2,5-diethylphospholan-1-yl.pdf | 317,42 kB | Adobe PDF | View/Open |
Title: | (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate |
Authors: | Schulz, S.; Fischer, C.; Drexler, H.-J.; Heller, D. |
Publishers Version: | https://doi.org/10.1107/S1600536810039577 |
Issue Date: | 2010 |
Published in: | Acta Crystallographica Section E: Structure Reports Online Vol. 66 (2010), No. 11 |
Publisher: | Chester : International Union of Crystallography |
Abstract: | The title compound, [Rh(C8H12)(C18H 36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate 2, 2-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) is 14.0 (1)°. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio. |
Keywords: | Crystal structure; Chemistry; Crystallography |
DDC: | 540 |
License: | CC BY 4.0 Unported |
Link to License: | https://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License