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| File | Description | Size | Format | |
|---|---|---|---|---|
| Schulz et al 2010, +-1,2-Bis2R,5R-2,5-diethylphospholan-1-yl.pdf | 317.42 kB | Adobe PDF | View/Open |
| Title: | (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate |
| Authors: | Schulz, S.; Fischer, C.; Drexler, H.-J.; Heller, D. |
| Publishers Version: | https://doi.org/10.1107/S1600536810039577 |
| Issue Date: | 2010 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online Vol. 66 (2010), No. 11 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | The title compound, [Rh(C8H12)(C18H 36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate 2, 2-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) is 14.0 (1)°. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio. |
| Keywords: | Crystal structure; Chemistry; Crystallography |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to License: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License
