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| File | Description | Size | Format | |
|---|---|---|---|---|
| Schulz et al 2010, +-1,2-Bis2R,5R-2,5-dimethylphospholan.pdf | 475 kB | Adobe PDF | View/Open |
| Title: | (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate |
| Authors: | Schulz, S.; Drexler, H.-J.; Heller, D. |
| Publishers Version: | https://doi.org/10.1107/S1600536810019859 |
| Issue Date: | 2010 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online Vol. 66 (2010), No. 6 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | The title compound, [Rh(C8H12)(C14H 28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η2, η2-coordinated cyclo-octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol-ecules in the asymmetric unit and intra-molecular P - Rh - P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo-octa-diene ligand as well as one BF4 anion. |
| Keywords: | Crystal structure; Chemistry; Crystallography |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to License: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License
