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Peulecke et al 2010, 2,2-Bisdiphenylphosphanylpropane.pdf336.27 kBAdobe PDFView/Open
Title: [2,2-Bis(diphenylphosphanyl)propane κ2P,P0] tetracarbonylchromium(0)dichloromethane monosolvate
Authors: Peulecke, N.Peitz, S.Müller, B.H.Spannenberg, A.Rosenthal, U.
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Issue Date: 2010
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 66 (2010), No. 11
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [Cr(C27H26P2)(CO) 4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC 4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 70.27 (2)°.
Keywords: Crystal structure; Chemistry; Crystallography
DDC: 540
License: CC BY 4.0 Unported
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