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Lamac et al 2009, 1-Dimethylsilyl-2-phenyl-3-g5-tetramethylcyclopentadienyl.pdf405,84 kBAdobe PDFView/Open
Title: [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III)
Authors: Lamač, M.Spannenberg, A.Arndt, P.Rosenthal, U.
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Issue Date: 2009
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 65 (2009), No. 11
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [Ti(C10H15)(C20H 26Si)], was obtained from the reaction of [Ti{5: 1-C5Me4(CH2)}(5-C 5Me5)] with the alkynylsilane PhC2SiMe 2H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si- H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.
Keywords: Crystal structure; Chemistry; Crystallography
DDC: 540
License: CC BY 4.0 Unported
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Appears in Collections:Chemie

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