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| File | Description | Size | Format | |
|---|---|---|---|---|
| Lamac et al 2009, 1-Dimethylsilyl-2-phenyl-3-g5-tetramethylcyclopentadienyl.pdf | 405,84 kB | Adobe PDF | View/Open |
| Title: | [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III) |
| Authors: | Lamač, M.; Spannenberg, A.; Arndt, P.; Rosenthal, U. |
| Publishers Version: | https://doi.org/10.1107/S1600536809044845 |
| Issue Date: | 2009 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online Vol. 65 (2009), No. 11 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | The title compound, [Ti(C10H15)(C20H 26Si)], was obtained from the reaction of [Ti{5: 1-C5Me4(CH2)}(5-C 5Me5)] with the alkynylsilane PhC2SiMe 2H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si- H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type. |
| Keywords: | Crystal structure; Chemistry; Crystallography |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to License: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License
