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Peitz et al 2009, BisN,N0-bis2,6-diisopropylphenylethane.pdf | 389,6 kB | Adobe PDF | View/Open |
Title: | Bis[N,N′-bis-(2,6-diisopropylphenyl)ethane-1,2-diimine] -1κ2 N,N′;2κ2 N,N′-tri - Trichlorido-1:2κ6 Cl:Clchlorido-1Cltetrahydrofuran- 2Odichromium(II) dichloromethane 4.5-solvate |
Authors: | Peitz, S.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U. |
Publishers Version: | https://doi.org/10.1107/S1600536809047266 |
Issue Date: | 2009 |
Published in: | Acta Crystallographica Section E: Structure Reports Online Vol. 65 (2009), No. 12 |
Publisher: | Chester : International Union of Crystallography |
Abstract: | In the mol-ecular structure of the title compound, [Cr2Cl4(C 26H36N2)2(C4H8O)] ·4.5CH2Cl2, the two CrII centers are bridged by three Cl atoms, forming a dinuclear complex. Each CrII center is coordinated by one chelating bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra-hydro-furan mol-ecule coordinates to the second CrII center. The coordination geometry at each CrII center can be best described as distorted octa-hedral. |
Keywords: | Crystal structure; Chemistry; Crystallography |
DDC: | 540 |
License: | CC BY 4.0 Unported |
Link to License: | https://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License