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Peitz et al 2009, BisN,N0-bis2,6-diisopropylphenylethane.pdf389,6 kBAdobe PDFView/Open
Title: Bis[N,N′-bis-(2,6-diisopropylphenyl)ethane-1,2-diimine] -1κ2 N,N′;2κ2 N,N′-tri - Trichlorido-1:2κ6 Cl:Clchlorido-1Cltetrahydrofuran- 2Odichromium(II) dichloromethane 4.5-solvate
Authors: Peitz, S.Peulecke, N.Müller, B.H.Spannenberg, A.Rosenthal, U.
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Issue Date: 2009
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 65 (2009), No. 12
Publisher: Chester : International Union of Crystallography
Abstract: In the mol-ecular structure of the title compound, [Cr2Cl4(C 26H36N2)2(C4H8O)] ·4.5CH2Cl2, the two CrII centers are bridged by three Cl atoms, forming a dinuclear complex. Each CrII center is coordinated by one chelating bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra-hydro-furan mol-ecule coordinates to the second CrII center. The coordination geometry at each CrII center can be best described as distorted octa-hedral.
Keywords: Crystal structure; Chemistry; Crystallography
DDC: 540
License: CC BY 4.0 Unported
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