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Title: [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
Authors: Hapke, M.Wöhl, A.Peitz, S.Müller, B.H.Spannenberg, A.Rosenthal, U.
Publishers Version: https://doi.org/10.1107/S1600536809003936
Issue Date: 2009
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 65 (2009), No. 3
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [NiBr2(C27H27NP2)], was synthesized by the reaction of NiBr2(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, PH2PN(iPr)PPH2, and two bromide ions in a distorted square-planar geometry.
Keywords: Crystal structure; Chemistry; Crystallography
DDC: 540
License: CC BY 4.0 Unported
Link to License: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie



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