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| File | Description | Size | Format | |
|---|---|---|---|---|
| Hapke et al 2009, trans-Di-l-acetato.pdf | 324,61 kB | Adobe PDF | View/Open |
| Title: | Trans-Di-μ-acetato-[μ-N,N-bis-(diphenyl-phosphino)aniline] bis-[chlorido-molybdenum(II)](Mo - Mo)-dichloro-methane-tetra-hydro-furan (1/0.3/1.7) |
| Authors: | Hapke, M.; Wöhl, A.; Peitz, S.; Spannenberg, A.; Rosenthal, U. |
| Publishers Version: | https://doi.org/10.1107/S1600536809007016 |
| Issue Date: | 2009 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online Vol. 65 (2009), No. 4 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | The mol-ecular structure of the title compound, [Mo2(CH 3COO)2Cl2(C30H25NP 2)]·0.3CH2Cl2·1.7C 4H8O, features an Mo - Mo dumbbell bridged by two acetate groups which are trans to each other. Perpendicular to the plane spanned by the acetate groups, the Ph2PN(Ph)PPh2 ligand bridges both Mo atoms, having a P - N - P angle of 114.09 (19)°. In a trans position to the PNP ligand are two Cl atoms, one on each molybdenum centre. The Mo - Mo bond distance is 2.1161 (9) Å, within the range known for Mo - Mo quadruple bonds. The Mo complex is located on a crystallographic twofold rotation axis which runs through the N - C bond of the ligand. The site occupation factors of the disordered solvent molecules were fixed to 0.15 for dichloromethane and 0.85 for tetrahydrofuran. © 2009. |
| Keywords: | Crystal structure; Chemistry; Crystallography |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to License: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
This item is licensed under a Creative Commons License
