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Title: (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate
Authors: Meissner, A.Selle, C.Drexler, H.-J.Heller, D.
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Issue Date: 2012
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 68 (2012), No. 3
Publisher: Chester : International Union of Crystallography
Abstract: In the title complex, [RhCl(C 44H 32OP 2)]·CH 3OH, the Rh I ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis-(diphenylphosphanyl)-1, 1′-binaphthyl (BINAP) ligand in a 4 mode, one P atom of the diphenylphosphanyl group and one Cl atom. The P=O group does not interact with the Rh I ion but accepts an O - H⋯O hydrogen bond from the methanol solvent molecule.
Keywords: data-to-parameter ratio = 13.5; mean σ(C-C) = 0.006 Å; R factor = 0.027; single-crystal X-ray study; T = 200 K; wR factor = 0.043
DDC: 540
License: CC BY 4.0 Unported
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