Please use this identifier to cite or link to this item: https://oar.tib.eu/jspui/handle/123456789/5579
Full metadata record
DC FieldValueLanguage
dc.rights.licenseCC BY 4.0 Unportedger
dc.contributor.authorHaehnel, M.-
dc.contributor.authorAltenburger, K.-
dc.contributor.authorSpannenberg, A.-
dc.contributor.authorArndt, P.-
dc.contributor.authorRosenthal, U.-
dc.date.accessioned2020-09-06T07:58:38Z-
dc.date.available2020-09-06T07:58:38Z-
dc.date.issued2012-
dc.identifier.urihttp://dx.doi.org/10.34657/4208-
dc.identifier.urihttps://oar.tib.eu/jspui/handle/123456789/5579
dc.description.abstractThe title dimeric zirconium complex, [Zr3(C20H 24)2S2]·C7H8, was obtained from the reaction of (ebthi)Zr(η2-Me3Si-C2-SiMe3) [ebthi is rac-1,2-bis(η5-4,5,6,7-tetrahydroinden-1-yl)ethane] and S=C=N-ada (ada = adamantan-1-yl) along with the formation of the isonitrile C N-ada. Each ZrIV atom is coordinated by the sterically hindered ebthi ligand and two μ-sulfide ligands in a strongly distorted tetrahedral geometry. The [ZrS]2 unit is almost planar (mean deviation from the best plane of the four atoms = 0.025Å). A -CH2-CH2- group in one ebthi ligand was disordered over two sites, with refined occupancy factors of 0.551(6) and 0.449(6). The asymmetric unit also contains a toluene solvent molecule.eng
dc.language.isoeng-
dc.publisherChester : International Union of Crystallography-
dc.relation.ispartofseriesActa Crystallographica Section E: Structure Reports Online Vol. 68 (2012), No. 11-
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/ger
dc.subjectdata-to-parameter ratio = 19.8eng
dc.subjectdisorder in main residueeng
dc.subjectmean ̄(C-C) = 0.003 Åeng
dc.subjectR factor = 0.027eng
dc.subjectsingle-crystal X-ray studyeng
dc.subjectT = 150 Keng
dc.subjectwR factor = 0.072eng
dc.subject.ddc540-
dc.titleDi-μ-sulfido-bis{[rac-1,2-bis(η5-4,5,6, 7-tetrahydroinden-1-yl)ethane]zirconium(IV)} toluene monosolvateeng
dc.typearticle-
dc.typeText-
dc.description.versionpublishedVersioneng
local.accessRightsopenAccess-
wgl.contributorLIKATger
wgl.subjectChemieger
wgl.typeZeitschriftenartikelger
dc.bibliographicCitation.volume68-
dc.bibliographicCitation.issue11-
dc.relation.doihttps://doi.org/10.1107/S1600536812044121-
dc.relation.issn1600-5368-
dcterms.bibliographicCitation.journalTitleActa Crystallographica Section E: Structure Reports Online-
local.identifier.doihttp://dx.doi.org/10.34657/4208-
Appears in Collections:Chemie

Files in This Item:
File Description SizeFormat 
Haehnel2012.pdf369.94 kBAdobe PDFView/Open


This item is licensed under a Creative Commons License Creative Commons