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Title: (η6-Benzene)(carbonato-κ2O,O') [dicyclohexyl(naphthalen-1-ylmethyl)phosphanejP] ruthenium(II) chloroform trisolvate
Authors: Gowrisankar, S.Neumann, H.Spannenberg, A.Beller, M.
Publishers Version: https://doi.org/10.1107/S1600536814014081
Issue Date: 2014
Published in: Acta Crystallographica Section E: Structure Reports Online Vol. 70 (2014), No. 7
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [Ru(CO3)(η6-C 6H6){(C6H11)2P(CH 2-C10H7)}]-3CHCl3, was synthesized by carbonation of [RuCl2-(η6-C6H 6){(C6H11)2P(CH2C 10H7)}] with NaHCO3in methanol at room temperature. The RuIIatom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding interactions between adjacent metal complexes and between the complexes and the solvent molecules. The asymmetric unit contains one metal complex and three chloroform solvent molecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloroform solvent molecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON.
Keywords: Data-to-parameter ratio = 19.9; Mean σ(C-C) = 0.007 Å; R factor = 0.041; Single-crystal X-ray study; Some non-H atoms missing; T = 150 K; WR factor = 0.110
DDC: 540
License: CC BY 4.0 Unported
Link to License: https://creativecommons.org/licenses/by/4.0/
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